Conformational dependence of 13C shielding and coupling constants for methionine methyl groups

نویسندگان
چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Environmental Dependence of Masses and Coupling Constants

We construct a class of scalar field models coupled to matter that lead to the dependence of masses and coupling constants on the ambient matter density. Such models predict a deviation of couplings measured on the Earth from values determined in low-density astrophysical environments, but do not necessarily require the evolution of coupling constants with the redshift in the recent cosmologica...

متن کامل

Quark mass dependence of pseudo-scalar masses and coupling constants

The dependence of pseudo-scalar masses and decay constants on the sea and valence quark masses is investigated in the pseudo-Goldstone boson sector of QCD with two light quark flavours. The sea quark masses are at present in the range 1 3 ms ≤ mud ≤ 2 3 ms whereas the valence quark masses satisfy 1 2 msea ≤ mval ≤ 2msea. The values of the Gasser-Leutwyler low energy constants L4, L5, L6 and L8 ...

متن کامل

Nuclear magnetic resonance studies of sperm whale myoglobin specifically enriched with 13C in the methionine methyl groups.

The Cepsilon methyl group of the 2 methionine residues in sperm whale myoglobin was enriched with respect to 13C. This was accomplished by treatment of the apomyoglobin at pH 4 at room temperature with a 100-fold proportion of 13CH3I to form an intermediate containing enriched S-methylmethionine. Unselective demethylation to regain the apomyoglobin structure was accomplished by treatment at pH ...

متن کامل

Density functional explorations of quadrupole coupling constants for BN, BP, AlN, and AlP graphene–like structures

Stabilizations and atomic level quadrupole coupling constant (CQ) properties have been investigated for graphene–like monolayers (G–monolayers) of boron nitride (BN), boron phosphide (BP), aluminum nitride (AlN), and aluminum phosphide (AlP) structures. To this aim, density functional theory (DFT) calculations have been performed to optimize the model structures and also to evaluate the CQ para...

متن کامل

Density functional explorations of quadrupole coupling constants for BN, BP, AlN, and AlP graphene–like structures

Stabilizations and atomic level quadrupole coupling constant (CQ) properties have been investigated for graphene–like monolayers (G–monolayers) of boron nitride (BN), boron phosphide (BP), aluminum nitride (AlN), and aluminum phosphide (AlP) structures. To this aim, density functional theory (DFT) calculations have been performed to optimize the model structures and also to evaluate the CQ para...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Journal of Biomolecular NMR

سال: 2010

ISSN: 0925-2738,1573-5001

DOI: 10.1007/s10858-010-9436-6